Araştırma Makalesi
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The enhanced polymer-coated graphite anode electrodes for the electrooxidation of glucose

Yıl 2023, Cilt: 11 Sayı: 1, 119 - 123, 01.07.2023

Aykut Çağlar

https://doi.org/10.51354/mjen.1231275

Öz

In this study, poly(N-Isopropylacrylamide) (PNIPAM), poly(acrylamide) (PAAM), poly(acrylic acid) (PAAc), and poly(methacrylic acid) (PMAc) polymers are synthesized by radical polymerization method. The chemical composition and surface morphology of the PMAc polymer are examined by micro-Raman spectroscopy and scanning electron microscopy (SEM). The electrochemical measurements are examined by cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) analyses for glucose (Glu) electrooxidation. The characterization analyses reveal that the polymer structure was formed. The electrochemical analysis results indicate that the PMAc/G electrode has higher catalytic activity, stability, and resistance compared to other electrodes with a specific activity of 1.7 mA/cm2.

Anahtar Kelimeler

graphite polymer glucose electrooxidation

Kaynakça

  • B. Ulas, A. Caglar, S. Yılmaz, U. Ecer, Y. Yilmaz, T. Sahan, H. Kivrak, Towards more active and stable PdAgCr electrocatalysts for formic acid electrooxidation: The role of optimization via response surface methodology, International Journal of Energy Research, 43 (2019) 8985-9000.
  • T. Avci Hansu, O. Sahin, A. Caglar, H. Kivrak, A remarkable Mo doped Ru catalyst for hydrogen generation from sodium borohydride: the effect of Mo addition and estimation of kinetic parameters, Reaction Kinetics, Mechanisms and Catalysis, 131 (2020) 661-676.
  • Z. Chen, X. Duan, W. Wei, S. Wang, B.-J. Ni, Recent advances in transition metal-based electrocatalysts for alkaline hydrogen evolution, Journal of Materials Chemistry A, 7 (2019) 14971-15005.
  • M. Cao, H. Cao, W. Meng, Q. Wang, Y. Bi, X. Liang, H. Yang, L. Zhang, M.-F. Lang, J. Sun, Nickel-copper oxide nanoflowers for highly efficient glucose electrooxidation, International Journal of Hydrogen Energy, 46 (2021) 28527-28536.
  • B. Ulas, A. Caglar, O. Sahin, H. Kivrak, Composition dependent activity of PdAgNi alloy catalysts for formic acid electrooxidation, J. Colloid Interface Sci., 532 (2018) 47-57.
  • A. Caglar, T. Sahan, M.S. Cogenli, A.B. Yurtcan, N. Aktas, H. Kivrak, A novel Central Composite Design based response surface methodology optimization study for the synthesis of Pd/CNT direct formic acid fuel cell anode catalyst, International Journal of Hydrogen Energy, 43 (2018) 11002-11011.
  • B. Ulas, A. Caglar, A. Kivrak, H. Kivrak, Atomic molar ratio optimization of carbon nanotube supported PdAuCo catalysts for ethylene glycol and methanol electrooxidation in alkaline media, Chemical Papers, 73 (2019) 425-434.
  • A. Çağlar, A. Aldemir, H. Kivrak, Alcohol electrooxidation study on carbon nanotube supported monometallic, Pt, Bi, and Ru catalysts, Fullerenes, Nanotubes and Carbon Nanostructures, 26 (2018) 863-870.
  • A. Caglar, H. Kivrak, Highly active carbon nanotube supported PdAu alloy catalysts for ethanol electrooxidation in alkaline environment, International Journal of Hydrogen Energy, 44 (2019) 11734-11743.
  • D. Atbas, A. Çağlar, H. Kivrak, A. Kivrak, Microwave Assisted Synthesis of Sn Promoted Pt Catalysts and Their Ethanol Electro-oxidation Activities, American Journal of Nanomaterials, 4 (2016) 8-11.
  • A. Caglar, D. Düzenli, I. Onal, I. Tezsevin, O. Sahin, H. Kivrak, A comparative experimental and density functional study of glucose adsorption and electrooxidation on the Au-graphene and Pt-graphene electrodes, International Journal of Hydrogen Energy, 45 (2020) 490-500.
  • A. Caglar, H. Kivrak, N. Aktas, A.O. Solak, Fabrication of Carbon-Doped Titanium Dioxide Nanotubes as Anode Materials for Photocatalytic Glucose Fuel Cells, Journal of Electronic Materials, 50 (2021) 2242-2253.
  • A. Caglar, T. Avci Hansu, O. Sahin, H. Kivrak, Fabrication of novel palladium-platinum based graphene/ITO electrodes and third metal addition effect through the glucose electrooxidation, Journal of Electroanalytical Chemistry, 918 (2022) 116505.
  • A. Caglar, B. Ulas, O. Sahin, H. Demir Kivrak, Few-layer graphene coated on indium tin oxide electrodes prepared by chemical vapor deposition and their enhanced glucose electrooxidation activity, Energy Storage, 1 (2019) e73.
  • A. Caglar, B. Ulas, O. Sahin, H. Kıvrak, Synthesis of in situ N-, S-, and B-doped few-layer graphene by chemical vapor deposition technique and their superior glucose electrooxidation activity, International Journal of Energy Research, 43 (2019) 8204-8216.
  • A. Brouzgou, S. Song, P. Tsiakaras, Carbon-supported PdSn and Pd3Sn2 anodes for glucose electrooxidation in alkaline media, Applied Catalysis B: Environmental, 158-159 (2014) 209-216.
  • J. Ryu, H.-S. Kim, H.T. Hahn, D. Lashmore, Carbon nanotubes with platinum nano-islands as glucose biofuel cell electrodes, Biosens. Bioelectron., 25 (2010) 1603-1608.
  • M. Irfan, X. Liu, S. Li, I.U. Khan, Y. Li, J. Wang, X. Wang, X. Du, G. Wang, P. Zhang, High-performance glucose fuel cell with bimetallic Ni–Co composite anchored on reduced graphene oxide as anode catalyst, Renewable Energy, 155 (2020) 1118-1126.
  • T. Ishimoto, Y. Hamatake, H. Kazuno, T. Kishida, M. Koyama, Theoretical study of support effect of Au catalyst for glucose oxidation of alkaline fuel cell anode, Applied Surface Science, 324 (2015) 76-81.
  • A. Eshghi, M. Kheirmand, Palladium nanoparticles supported on carbon black powder as an effective anodic catalyst for application in a direct glucose alkaline fuel cell, Iranian Journal of Hydrogen & Fuel Cell, 3 (2016) 11-17.
  • J.-S. Ye, Z.-T. Liu, C.-C. Lai, C.-T. Lo, C.-L. Lee, Diameter effect of electrospun carbon fiber support for the catalysis of Pt nanoparticles in glucose oxidation, Chemical Engineering Journal, 283 (2016) 304-312.
  • S. Ghosh, S. Das, M.E.G. Mosquera, Conducting Polymer-Based Nanohybrids for Fuel Cell Application, Polymers, 12 (2020) 2993.
  • S. Ghosh, T. Maiyalagan, R.N. Basu, Nanostructured conducting polymers for energy applications: towards a sustainable platform, Nanoscale, 8 (2016) 6921-6947.
  • K. Dutta, S. Das, D. Rana, P.P. Kundu, Enhancements of catalyst distribution and functioning upon utilization of conducting polymers as supporting matrices in DMFCs: a review, Polymer Reviews, 55 (2015) 1-56.
  • K. Dutta, P.P. Kundu, A review on aromatic conducting polymers-based catalyst supporting matrices for application in microbial fuel cells, Polymer Reviews, 54 (2014) 401-435.
  • L. Fan, T. Gao, Applications of nanoscale polypyrrole proton exchange membrane in microbial fuel cells, Int. J. Electrochem. Sci, 14 (2019) 470-480.
  • Q. Zhou, G. Shi, Conducting polymer-based catalysts, J. Am. Chem. Soc., 138 (2016) 2868-2876.
  • Inamuddin, H.A. Kashmery, Ternary graphene@polyaniline-TiO2 composite for glucose biofuel cell anode application, International Journal of Hydrogen Energy, 44 (2019) 22173-22180.
  • R. Perveen, A. Nasar, S. Kanchi, H.A. Kashmery, Development of a ternerry condunting composite (PPy/Au/CNT@ Fe3O4) immobilized FRT/GOD bioanode for glucose/oxygen biofuel cell applications, International Journal of Hydrogen Energy, 46 (2021) 3259-3269.
  • A. Nasar, M.M. Rahman, Applications of chitosan (CHI)-reduced graphene oxide (rGO)-polyaniline (PAni) conducting composite electrode for energy generation in glucose biofuel cell, Sci. Rep., 10 (2020) 1-12.
  • O.F. Er, A. Caglar, H. Kivrak, Enhanced electrochemical glucose oxidation in alkaline solution over indium decorated carbon supported palladium nanoparticles, Mater. Chem. Phys., 254 (2020) 123318.
  • R.A. Escalona-Villalpando, M.P. Gurrola, G. Trejo, M. Guerra-Balcázar, J. Ledesma- García, L.G. Arriaga, Electrodeposition of gold on oxidized and reduced graphite surfaces and its influence on glucose oxidation, Journal of Electroanalytical Chemistry, 816 (2018) 92-98.
  • T. Rafaïdeen, S. Baranton, C. Coutanceau, Highly efficient and selective electrooxidation of glucose and xylose in alkaline medium at carbon supported alloyed PdAu nanocatalysts, Applied Catalysis B: Environmental, 243 (2019) 641-656.
  • A. Both Engel, M. Bechelany, O. Fontaine, A. Cherifi, D. Cornu, S. Tingry, One-Pot Route to Gold Nanoparticles Embedded in Electrospun Carbon Fibers as an Efficient Catalyst Material for Hybrid Alkaline Glucose Biofuel Cells, ChemElectroChem, 3 (2016) 629-637.
  • A. Caglar, D. Düzenli, I. Onal, I. Tezsevin, O. Sahin, H. Kivrak, A novel experimental and density functional theory study on palladium and nitrogen doped few layer graphene surface towards glucose adsorption and electrooxidation, J. Phys. Chem. Solids, 150 (2021) 109684.
  • T. Chhabra, J. Rohilla, V. Krishnan, Nanoarchitectonics of phosphomolybdic acid supported on activated charcoal for selective conversion of furfuryl alcohol and levulinic acid to alkyl levulinates, Molecular Catalysis, 519 (2022) 112135.

Yıl 2023, Cilt: 11 Sayı: 1, 119 - 123, 01.07.2023

Aykut Çağlar

https://doi.org/10.51354/mjen.1231275

Öz

Kaynakça

  • B. Ulas, A. Caglar, S. Yılmaz, U. Ecer, Y. Yilmaz, T. Sahan, H. Kivrak, Towards more active and stable PdAgCr electrocatalysts for formic acid electrooxidation: The role of optimization via response surface methodology, International Journal of Energy Research, 43 (2019) 8985-9000.
  • T. Avci Hansu, O. Sahin, A. Caglar, H. Kivrak, A remarkable Mo doped Ru catalyst for hydrogen generation from sodium borohydride: the effect of Mo addition and estimation of kinetic parameters, Reaction Kinetics, Mechanisms and Catalysis, 131 (2020) 661-676.
  • Z. Chen, X. Duan, W. Wei, S. Wang, B.-J. Ni, Recent advances in transition metal-based electrocatalysts for alkaline hydrogen evolution, Journal of Materials Chemistry A, 7 (2019) 14971-15005.
  • M. Cao, H. Cao, W. Meng, Q. Wang, Y. Bi, X. Liang, H. Yang, L. Zhang, M.-F. Lang, J. Sun, Nickel-copper oxide nanoflowers for highly efficient glucose electrooxidation, International Journal of Hydrogen Energy, 46 (2021) 28527-28536.
  • B. Ulas, A. Caglar, O. Sahin, H. Kivrak, Composition dependent activity of PdAgNi alloy catalysts for formic acid electrooxidation, J. Colloid Interface Sci., 532 (2018) 47-57.
  • A. Caglar, T. Sahan, M.S. Cogenli, A.B. Yurtcan, N. Aktas, H. Kivrak, A novel Central Composite Design based response surface methodology optimization study for the synthesis of Pd/CNT direct formic acid fuel cell anode catalyst, International Journal of Hydrogen Energy, 43 (2018) 11002-11011.
  • B. Ulas, A. Caglar, A. Kivrak, H. Kivrak, Atomic molar ratio optimization of carbon nanotube supported PdAuCo catalysts for ethylene glycol and methanol electrooxidation in alkaline media, Chemical Papers, 73 (2019) 425-434.
  • A. Çağlar, A. Aldemir, H. Kivrak, Alcohol electrooxidation study on carbon nanotube supported monometallic, Pt, Bi, and Ru catalysts, Fullerenes, Nanotubes and Carbon Nanostructures, 26 (2018) 863-870.
  • A. Caglar, H. Kivrak, Highly active carbon nanotube supported PdAu alloy catalysts for ethanol electrooxidation in alkaline environment, International Journal of Hydrogen Energy, 44 (2019) 11734-11743.
  • D. Atbas, A. Çağlar, H. Kivrak, A. Kivrak, Microwave Assisted Synthesis of Sn Promoted Pt Catalysts and Their Ethanol Electro-oxidation Activities, American Journal of Nanomaterials, 4 (2016) 8-11.
  • A. Caglar, D. Düzenli, I. Onal, I. Tezsevin, O. Sahin, H. Kivrak, A comparative experimental and density functional study of glucose adsorption and electrooxidation on the Au-graphene and Pt-graphene electrodes, International Journal of Hydrogen Energy, 45 (2020) 490-500.
  • A. Caglar, H. Kivrak, N. Aktas, A.O. Solak, Fabrication of Carbon-Doped Titanium Dioxide Nanotubes as Anode Materials for Photocatalytic Glucose Fuel Cells, Journal of Electronic Materials, 50 (2021) 2242-2253.
  • A. Caglar, T. Avci Hansu, O. Sahin, H. Kivrak, Fabrication of novel palladium-platinum based graphene/ITO electrodes and third metal addition effect through the glucose electrooxidation, Journal of Electroanalytical Chemistry, 918 (2022) 116505.
  • A. Caglar, B. Ulas, O. Sahin, H. Demir Kivrak, Few-layer graphene coated on indium tin oxide electrodes prepared by chemical vapor deposition and their enhanced glucose electrooxidation activity, Energy Storage, 1 (2019) e73.
  • A. Caglar, B. Ulas, O. Sahin, H. Kıvrak, Synthesis of in situ N-, S-, and B-doped few-layer graphene by chemical vapor deposition technique and their superior glucose electrooxidation activity, International Journal of Energy Research, 43 (2019) 8204-8216.
  • A. Brouzgou, S. Song, P. Tsiakaras, Carbon-supported PdSn and Pd3Sn2 anodes for glucose electrooxidation in alkaline media, Applied Catalysis B: Environmental, 158-159 (2014) 209-216.
  • J. Ryu, H.-S. Kim, H.T. Hahn, D. Lashmore, Carbon nanotubes with platinum nano-islands as glucose biofuel cell electrodes, Biosens. Bioelectron., 25 (2010) 1603-1608.
  • M. Irfan, X. Liu, S. Li, I.U. Khan, Y. Li, J. Wang, X. Wang, X. Du, G. Wang, P. Zhang, High-performance glucose fuel cell with bimetallic Ni–Co composite anchored on reduced graphene oxide as anode catalyst, Renewable Energy, 155 (2020) 1118-1126.
  • T. Ishimoto, Y. Hamatake, H. Kazuno, T. Kishida, M. Koyama, Theoretical study of support effect of Au catalyst for glucose oxidation of alkaline fuel cell anode, Applied Surface Science, 324 (2015) 76-81.
  • A. Eshghi, M. Kheirmand, Palladium nanoparticles supported on carbon black powder as an effective anodic catalyst for application in a direct glucose alkaline fuel cell, Iranian Journal of Hydrogen & Fuel Cell, 3 (2016) 11-17.
  • J.-S. Ye, Z.-T. Liu, C.-C. Lai, C.-T. Lo, C.-L. Lee, Diameter effect of electrospun carbon fiber support for the catalysis of Pt nanoparticles in glucose oxidation, Chemical Engineering Journal, 283 (2016) 304-312.
  • S. Ghosh, S. Das, M.E.G. Mosquera, Conducting Polymer-Based Nanohybrids for Fuel Cell Application, Polymers, 12 (2020) 2993.
  • S. Ghosh, T. Maiyalagan, R.N. Basu, Nanostructured conducting polymers for energy applications: towards a sustainable platform, Nanoscale, 8 (2016) 6921-6947.
  • K. Dutta, S. Das, D. Rana, P.P. Kundu, Enhancements of catalyst distribution and functioning upon utilization of conducting polymers as supporting matrices in DMFCs: a review, Polymer Reviews, 55 (2015) 1-56.
  • K. Dutta, P.P. Kundu, A review on aromatic conducting polymers-based catalyst supporting matrices for application in microbial fuel cells, Polymer Reviews, 54 (2014) 401-435.
  • L. Fan, T. Gao, Applications of nanoscale polypyrrole proton exchange membrane in microbial fuel cells, Int. J. Electrochem. Sci, 14 (2019) 470-480.
  • Q. Zhou, G. Shi, Conducting polymer-based catalysts, J. Am. Chem. Soc., 138 (2016) 2868-2876.
  • Inamuddin, H.A. Kashmery, Ternary graphene@polyaniline-TiO2 composite for glucose biofuel cell anode application, International Journal of Hydrogen Energy, 44 (2019) 22173-22180.
  • R. Perveen, A. Nasar, S. Kanchi, H.A. Kashmery, Development of a ternerry condunting composite (PPy/Au/CNT@ Fe3O4) immobilized FRT/GOD bioanode for glucose/oxygen biofuel cell applications, International Journal of Hydrogen Energy, 46 (2021) 3259-3269.
  • A. Nasar, M.M. Rahman, Applications of chitosan (CHI)-reduced graphene oxide (rGO)-polyaniline (PAni) conducting composite electrode for energy generation in glucose biofuel cell, Sci. Rep., 10 (2020) 1-12.
  • O.F. Er, A. Caglar, H. Kivrak, Enhanced electrochemical glucose oxidation in alkaline solution over indium decorated carbon supported palladium nanoparticles, Mater. Chem. Phys., 254 (2020) 123318.
  • R.A. Escalona-Villalpando, M.P. Gurrola, G. Trejo, M. Guerra-Balcázar, J. Ledesma- García, L.G. Arriaga, Electrodeposition of gold on oxidized and reduced graphite surfaces and its influence on glucose oxidation, Journal of Electroanalytical Chemistry, 816 (2018) 92-98.
  • T. Rafaïdeen, S. Baranton, C. Coutanceau, Highly efficient and selective electrooxidation of glucose and xylose in alkaline medium at carbon supported alloyed PdAu nanocatalysts, Applied Catalysis B: Environmental, 243 (2019) 641-656.
  • A. Both Engel, M. Bechelany, O. Fontaine, A. Cherifi, D. Cornu, S. Tingry, One-Pot Route to Gold Nanoparticles Embedded in Electrospun Carbon Fibers as an Efficient Catalyst Material for Hybrid Alkaline Glucose Biofuel Cells, ChemElectroChem, 3 (2016) 629-637.
  • A. Caglar, D. Düzenli, I. Onal, I. Tezsevin, O. Sahin, H. Kivrak, A novel experimental and density functional theory study on palladium and nitrogen doped few layer graphene surface towards glucose adsorption and electrooxidation, J. Phys. Chem. Solids, 150 (2021) 109684.
  • T. Chhabra, J. Rohilla, V. Krishnan, Nanoarchitectonics of phosphomolybdic acid supported on activated charcoal for selective conversion of furfuryl alcohol and levulinic acid to alkyl levulinates, Molecular Catalysis, 519 (2022) 112135.
Toplam 36 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Araştırma Makalesi
Yazarlar

Aykut Çağlar 0000-0002-0681-1096

Erken Görünüm Tarihi 23 Haziran 2023
Yayımlanma Tarihi 1 Temmuz 2023
Yayımlandığı Sayı Yıl 2023 Cilt: 11 Sayı: 1

Kaynak Göster

APA Çağlar, A. (2023). The enhanced polymer-coated graphite anode electrodes for the electrooxidation of glucose. MANAS Journal of Engineering, 11(1), 119-123. https://doi.org/10.51354/mjen.1231275
AMA Çağlar A. The enhanced polymer-coated graphite anode electrodes for the electrooxidation of glucose. MJEN. Temmuz 2023;11(1):119-123. doi:10.51354/mjen.1231275
Chicago Çağlar, Aykut. “The Enhanced Polymer-Coated Graphite Anode Electrodes for the Electrooxidation of Glucose”. MANAS Journal of Engineering 11, sy. 1 (Temmuz 2023): 119-23. https://doi.org/10.51354/mjen.1231275.
EndNote Çağlar A (01 Temmuz 2023) The enhanced polymer-coated graphite anode electrodes for the electrooxidation of glucose. MANAS Journal of Engineering 11 1 119–123.
IEEE A. Çağlar, “The enhanced polymer-coated graphite anode electrodes for the electrooxidation of glucose”, MJEN, c. 11, sy. 1, ss. 119–123, 2023, doi: 10.51354/mjen.1231275.
ISNAD Çağlar, Aykut. “The Enhanced Polymer-Coated Graphite Anode Electrodes for the Electrooxidation of Glucose”. MANAS Journal of Engineering 11/1 (Temmuz 2023), 119-123. https://doi.org/10.51354/mjen.1231275.
JAMA Çağlar A. The enhanced polymer-coated graphite anode electrodes for the electrooxidation of glucose. MJEN. 2023;11:119–123.
MLA Çağlar, Aykut. “The Enhanced Polymer-Coated Graphite Anode Electrodes for the Electrooxidation of Glucose”. MANAS Journal of Engineering, c. 11, sy. 1, 2023, ss. 119-23, doi:10.51354/mjen.1231275.
Vancouver Çağlar A. The enhanced polymer-coated graphite anode electrodes for the electrooxidation of glucose. MJEN. 2023;11(1):119-23.
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